Iron cyclopentadienone complexes derived from C2-symmetric bis-propargylic alcohols; preparation and applications to catalysis.

نویسندگان

  • Roy Hodgkinson
  • Alessandro Del Grosso
  • Guy Clarkson
  • Martin Wills
چکیده

A series of complexes containing the iron-cyclopentadienone structure were prepared by cyclising bis-propargylic alcohols and their derivatives with iron pentacarbonyl. The resulting complexes were characterised and tested in the catalysis of ketone reduction and alcohol oxidation. The complexes are competent catalysts for ketone reduction and alcohol oxidations.

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عنوان ژورنال:
  • Dalton transactions

دوره 45 9  شماره 

صفحات  -

تاریخ انتشار 2016